It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Chloride stress corrosion cracking inspectioneering. It discusses constantstrain, constantload, bending, and uniaxial tension testing and how they compare when evaluating smooth and precracked test specimens under elasticstrain, plasticstrain, and residualstress conditions. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Figure 8 effect of chloride added as nacl on cracking of. Optical microscopy images of exposed sample 5 that presented clear evidence of cracking on the surface. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. Why does chloride stress corrosion cracking and pascc only. Stress corrosion cracking behaviour of lean duplex. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. The susceptibility of 2205 dss to scc at open circuit potential and at various anodic potentials was evaluated. Feb 15, 2017 a great concern for the longterm integrity of canisters located near the coastline is chloride induced stress corrosion cracking of austenitic stainless steels 3,4,5. Stress corrosion cracking in the necessary condition is to have tensile strength.
Chloride cracking of austenitic stainless steels 300 series ss is an offshoot of cui, and theres nothing really magical about it. This type of failure is referred to as stress corrosion cracking scc. Chloride stress corrosion cracking metal and metallurgy. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. First, the part must be stressed, either from an applied force or due to residual stress usually from forming. Pdf stresscorrosion cracking behaviour of leanduplex. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Corrosionpedia explains micrograph by conducting proper research, the development of substances with outstanding resistance to corrosion and longer lifespan can be achieved. The effects of prior cold work cw and sensitization treatment on the stress corrosion cracking scc behaviour of type 304 stainless steels have been studied in chloride solutions using electrochemical tests and magnesium chloride tests with ubend specimen. High chloride levels contribute to chloride stress corrosion cracking. The stress can be externally applied or it can be an internal residual stress. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stress corrosion cracking behavior of nickel base alloys.
The required tensile stresses may be in the form of directly applied stresses or in the form of residual. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. A bent nicu monel 400 alloy tube, which operated as part of a pipeline in a petrochemical distillery installation, failed by throughthickness cracking. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Chloride stress corrosion cracking cscc is a type of intergranular corrosion.
Prevention of external chloride stress corrosion cracking. Pitting is considered to be more dangerous than uniform corrosion damage because it is more difficult to detect, predict and design against. They observed stress corrosion cracking scc in potentials near the ocp, and hydrogen assisted cracking hac in higher cathodic potentials stress corrosion cracking scc is the growth of crack formation in a corrosive environment. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. Avoiding stress corrosion cracking of carbon low alloy and. Stress corrosion cracking in pipelines begins when small cracks develop on the external surface of buried pipelines. Chloride stress corrosion cracking in bfw preheater in. Intergranular stress corrosion cracking an overview. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched.
Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. It is related to the low constant tensile stress of an alloy exposed to the corrosive environment. Alloy 825 is more resistant to stress corrosion cracking in chloride solutions. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. The reason why steam condensate is commonly used to hydrotest ss piping. This article commences with a discussion on the characteristics of stress corrosion cracking scc and describes crack initiation and propagation during scc. Stresscorrosion cracking failure analysis and prevention.
Pitting corrosion facts and how to reduce the risk. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Temperature is a significant environmental factor affecting cracking. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Corrosion resistance of stainless steels and welding. The combination of the high molybdenum and chromium content, along with the addition of tungsten, make alloy c276 highly resistant to chloride stress corrosion cracking. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. The tower provided a caustic solution naoh to remove hcl from the stream, before the latter was directed to a burner. Chloride stress corrosion cracking stainless steels the three conditions that must be present for chloride stress corrosion to occur are as follows. Why does chloride stress corrosion cracking and pascc only happens in austenitic ss. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Micrograph of chloride stress corrosion cracking of austenitic stainless steel. Pitting corrosion is a localized form of corrosion by which cavities or holes are produced in the material. Branched cracking is a common characteristic of stress corrosion cracking. Alloy c276 has excellent corrosion resistance in both oxidizing and reducing environments. The aim of this project was to produce type 304 containers with intentional stress corrosion cracks, to serve as test samples for future weld repair trials. Micrograph stress corrosion cracking austenitic stainless. This article commences with a discussion on the characteristics of stresscorrosion cracking scc and describes crack initiation and propagation during scc. T651 are susceptible to stress corrosion cracking in chloride solution naclj while they both alloys seem to resist stress corrosion cracking in methyl alcohol, ethyl alcohol, isopropyl alcohol and demineralized distilled water. In contrast to hsc and ssc, stress corrosion cracking scc, defined as the cracking of a material produced by the combined action of corrosion and sustained tensile stress residual or applied, is an anodic process that takes place in a region where the passive film becomes unstable. Stress corrosion cracking of brittle fracture surface, but it may also occur in high toughness materials. In the power production plants, the alloy is used in superheater and reheater tubes.
Slow strain rate testing was performed at a strain rate of 4. Chlorideinduced corrosion behavior of stainless steel and. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range.
Chloride stress corrosion cracking stainless steel the three conditions that must be present for chloride stress corrosion to occur are as follows. A great concern for the longterm integrity of canisters located near the coastline is chlorideinduced stress corrosion cracking of austenitic stainless steels 3,4,5. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. C276 has excellent corrosion resistance in both oxidizing and reducing environments. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. The pipeline was used to carry a stream of gaseous hydrocarbons containing hydrochloric acid hcl into a reaction tower. Due to this very prevalent scc mechanism in the presence of chlorides, this situation has been given its own name. It discusses constantstrain, constantload, bending, and uniaxial tension testing and how they compare when evaluating smooth and precracked test specimens under elasticstrain, plasticstrain, and residual stress conditions. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Chloride stress corrosion cracking stainless steels. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material.
While it is rare, formed parts can develop fractures after they are placed in service. They were branchy and transgranular caused by contact to chloride ions and residual tensile stress in the steel. This article describes the incubation, nucleation, and propagation of stress corrosion cracking and how to evaluate it using standard tests. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Prevention of external chloride stress corrosion cracking of. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Pitting corrosion may occur in stainless steels in neutral or acid solutions containing halides, primarily chlorides cl, such as seawater. This article describes the incubation, nucleation, and propagation of stresscorrosion cracking and how to evaluate it using standard tests. Micrograph of stress corrosion cracking in austenitic stainless steel type 304. The micrograph x500 illustrates intergranular scc of an inconel heat exchanger tube with the crack following the grain boundaries. Apr 15, 20 our metallographs light microscopes are capable of examinations at magnifications from 15x to 1,000x.
Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless steel is a non magnetic alloy consisting of iron. Pitting corrosion is a form of localized corrosion, which produces attacks in the form of spots or pits. Pitting corrosion attacks most often take place at points where the passive layer might be. Investigation of the effect of low temperature aging on. Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless steel is a nonmagnetic alloy consisting of iron.
When viewed at high magnification the fracture surface of a component that has failed due to stress corrosion cracking has a faceted and granular appearance lefthand image below. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. The mechanism for igscc of pipeline steels apix65 is based on the presence of hydroxyl ions at the steelelectrolyte interface, which are formed by the applied cathodic current to protect the structure 71. Pdf stress corrosion cracking scc of nickelbased alloys.
The corrosion resistance of stainless steels that have been sensitized, can be returned by taking the temperature of the entire component high enough to return the chromium into solution and then cooling rapidly. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Table 6 stress corrosion cracking test results from ubend specimens exposed to irradiated 5 water, crushed. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. It is called chloride stress corrosion cracking cscc of austenitic stainless steels, and is one of the main factors to consider when evaluating the corrosion resistance of stainless steels for any application. Jul 17, 2017 in other words, the crack sides have experienced metal loss from corrosion. Stress corrosion cracking behavior of 2205 duplex stainless. The stress corrosion cracking scc behavior of 2205 duplex stainless steel dss in 26 wt% nacl solution at 90c was investigated. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Incoloy 800 is used in the chemical plants for components of heat exchangers and transmission pipes of nitric acid solutions that need to prevent attack of chloride stress corrosion cracking.
If you have insulated solid stainless steel equipment operating in the cui temperature range you are likely to eventually experience external chloride stress corrosion cracking ecscc. Stress corrosion cracking susceptibility of 304l substrate. Stress corrosion cracking scc stress corrosion cracking is to bear the stress of the alloy in the corrosive environment because of strong expansion of the alternate failure pattern of a generic term. Four factors, are required before stress corrosion cracking can occur. Marine atmospheric scc of unsensitized stainless steel rock. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments 1. Chloride stress corrosion cracking methods of minimizing. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. A comparison of stress corrosion cracking susceptibility. In a method of increasing intergranular stress corrosion cracking resistance of alloy 718 in water reactor environments, the alloy is heat treated at a high annealing temperature to dissolve precipitates. Stresscorrosion cracking of a monel 400 tube springerlink. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. Chloride stress corrosion cracking cscc of aisi 304 austenitic stainless steel are the most important corrosion processes that affect the performance of this stainless steel.
Corrosion and scc issues in watercooled nuclear power plants have been extensive, with intergranular stress corrosion cracking igscc and irradiationassisted stress corrosion iascc observed in numerous nickel and ironbased piping and heat exchanger materials 147161. That chlorine can generate a worrisome amount of chloride though if the downstream process used can concentrate that tiny amount of chloride manyfold over time e. The combination of the high molybdenum and chromium content, along with the addition of tungsten, make alloy c276 highly resistant to chloride stress corrosion cracking, pitting, crevice corrosion and general corrosion. Other than that, other factors that contribute to scc in stainless steel is sensitization treatment since sensitization occurs because of the chromium depletion. The micrograph above x500 illustrates intergranular scc of an inconel heat exchanger tube with the crack following the grain boundaries.
Titanium showed some susceptibility to scc in methanol, while no such. Chloride stress corrosion cracking in austenitic stainless. Intergranular stress corrosion cracking igscc is more common than transgranular scc. What causes stress corrosion cracking in pipelines. Observations of corrosion product formation and stress corrosion cracking on brass samples exposed to 5 ammonia environments figure 5. Stress corrosion cracking behaviour of lean duplex stainless. Stress corrosion scc degradation and surface engineering. Dec 16, 2014 the stress corrosion scc is defined as an environmentally induced cracking eic, which is a minimal uniform corrosion due to the environment resulting in a brittle fracture in a ductile alloy. The stresscorrosion cracking scc behaviour of two leanduplex stainless steels dss 2304 and ldss 2404 was studied by slow strainrate tests ssrt in 20% nacl solution at 80 c ph about 6. Aisi 304 stainless steel ss is one of the candidate materials used for dry storage canisters of spent nuclear fuel as an interim storage measure before final disposal 1,2. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Stress corrosion cracking scc is the simultaneous action of a tensile stress and an aggressive environment on an alloy system to produce a brittle fracture in a normally ductile material at stress levels far below engineering design limits. Nearneutralph scc is less temperaturedependent than highph scc.
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